Monooxo-bridged Binuclear Molybdenum () Complexes ()

[摘要] The monooxo-bridged binuclear molybdenum(¥´) complexes, Mo2O3(NCS)4(Bipy)2 (Bipy = bipyridine), Mo2O3(NCS)4(Phen)2 (Phen = 1,10-phenanthroline), and Mo2O3(NCS)4(Ox)2(OxH)2 (Ox = oxinato and OxH = oxine) have been prepared. Their electronic and IR spectra, electric conductivity, and magnetic susceptibility were measured. From the results all of th complexes turned out to be electroneutral dimers with about 0.5 BM, and in the oxine complex, Mo2O3(NCS)2(Ox)2(OxH)2, the oxine seems to bind partly as monodentate and partly as bidentate molecule.

[学科分类] 化学（综合）