A Synthesis of Tungsten Complexes with Oxine, Aniline or Pyridine in Organic Solvent

[摘要] The insoluble tungsten complexes with 8-hydroxy quinoline (oxine=Hox), aniline (A), and pyridine(Py) in several organic solvents have been synthesized. Using the different solvents with oxine, two different complexes have been synthesized in dichloromethane and dimethylformamide(DMF), respectively. Only one kind of complex has been synthesized with aniline in dichloromethane and with pyridine in acetone. The complexes may be formulated as [WCl2(Hox)2], [WO2(Ox2)], [WCl3A3], and [WO2ClPy] by the results of elemental analysis, infrared spectral data, and thermogravimetric analysis.

[学科分类] 化学（综合）