A Study on the Tungsten () Complexes with the Organic Acid Anhydrides

[摘要] Dichloro-dioxo-tungsten(¥µ) complexes containing oxygen donor in anhydrous organic acid have been synthesized. Sodium tungstate reacts with acetylchlorides to produce the mononuclear complexes, yellow powder having WO2Cl2(RCO)2O as general formula. Their chemical properties and the possible structure are proposed by the results of spectral data and chemical observation.

[学科分类] 化学（综合）