Calculation of the Dipole Moments for Tetrahedral and Square Planar [M()N2S2] Type Complexes [M() = Ni(), Co(), Cu() or Zn()]
[摘要] The dipole moments for square planar and tetrahedral [M(¥±) N2S2] type complexes are calculated, using the expansion method for spherical harmonics [M(¥±) = Co(¥±), Ni(¥±), Cu(¥±) or Zn(¥±)]. The calculated values of the dipole moments for these complexes are in the range of the experimental values. The possible structures for these complexes in benzene solution are discussed on the basis of the calculated dipole moments and the the magnetic properties.
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[效力级别] [学科分类] 化学(综合)
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