Calculation of the Dipole Mometns for Octahedral [M()Cl2O2N2] Square Planar and Tetrahedral [Pd()X2Y2] Type Complexes [M() = Ni() or Co(), X = N and Y = O or S]

[摘要] The dipole moments for octahedral [M(¥±)Cl2N2O2], square planar and tetrahedral [Pd(¥±)X2Y2] type complexes are calculated, using the approximate molecular orbital theory [M(¥±) = Ni(¥±) or Co(¥±), X = N and Y = O or S]. The calculated dipole moments for these complexes are in reasonable agreement with the experimental values. The possible structures for these complexes are investigated on the basis of the calculated dipole moments.

[学科分类] 化学（综合）