Synthesis and Characterization of Oxalatoferrate () Complexes

[摘要] Amine salts of five tetrahedral and three octahedral oxalatoferrate(¥²) complexes have been prepared including pyridinium salts of unreported oxalate complex ions [FeC2O4Br2]-, [FeC2O4(NCS)4]3- and [Fe2(C2O4)3Cl4]4-, the latter being most photoreactive. The structural aspects of these new complex ions as well as of other oxalatoferrates(¥²) have been discussed based on their analytical data and infrared spectra. The results of molar conductivity and magnetic susceptibility measurements of all these oxalatoferrate(¥²) complexes were also presented.

[学科分类] 化学（综合）