Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (). Substituted Pyridinium Salts of Oxopentaisothiocyanatomolybdates()

[摘要] Benzoylpyridinium and lutidinium salts containing [MoO(NCS)5]2- have been synthesized. The complexes have been characterized by spectroscopic, magnetic susceptibility and conductivity studies. Benzoylpyridinium and lutidinium oxopentaisothiocyanatomolybdates(¥´) arise from d-d and charge transfer transitions. The magnetic moments of the complexes are close to the spin-only values. The complex anions are mononuclear containing N-bonded NCS- ligand.

[学科分类] 化学（综合）