Solvolysis of p-Nitrobenzyl chloride in the Ethanol-water Mixture

[摘要] The thermodynamic parameters for the solvolysis of the p-nitrobenzyl chloride which take place in the ethanol-water mixture media were determined. From the application of this data to the formula ¥äM¥ÄH¡Á = a'Y + b¥äM¥ÄS¡Á the following conclusion was obtained. The substrate constant a' for this reaction was not varied in the media which contain more than 50% alcohol and less than 50% alcohol. From this, it is clear that the mechanism of this reaction is the same both in the water-rich solvent and in the alcohol-rich solvent.

[学科分类] 化学（综合）