Transient State Theory of Significant Liquid Structure

[摘要] In formulating the Transient State Theory of Significant Liquid Structure it is assumed that there exist holes of molecular size in liquids and that the liquid state is partitioned in three states, namely, solid-like state, representing the molecules apart from holes; gas-like state, representing the molecules jumping into the holes; and the transient state, representing the molecules in a possible state of jumping into the holes by aquiring the strain energy due to the holes. It is found that the partition function derived according to the proposed theory can be applied to the liquids of argon, nitrogen, benzene, chloroform, and carbon disulfide with good accuracy.

[学科分类] 化学（综合）