Spectrophotometric determination of Cobalt by means of Co-EDTA butyl ester Complex

[摘要] A new method of cobalt determination has been developed by employing ethylenediamine tetrabutyl acetate(EDTA-butyl ester) synthesized from EDTA and Butyl alcohol. The synthesized EDTA ester dissolved in butyl alcohol extracts various metal ions from aqueous solutions. Cobaltous ion extracted into organic phase containing EDTA ester to form Co (II)-EDTA butyl ester complex is back extracted into alkaline aqueous phase forming a stable pink colored complex of Co (III). The optimum condition for spectrophotometric determination of cobalt via the new complex has been established. The absorption peak occurs at 540m¥ì and Beer's law was obeyed over the concentration range of 0¡­50 ¥ìg/ml of cobalt.

[学科分类] 化学（综合）