Calculation of the Magnetic Moments and the Dipolar Shifts for d1 and d2 Complexes in a Strong Ligand Field of Trigonal Symmetry

[摘要] A method to calculate the magnetic moments for d1 and d2 complexes in a strong crystal field of trigonal symmetry has been developed in this work choosing the trigonal axis (�?) as the quantization axis. The calculated magnetic moments using this method for d1 and d2 complexes in a strong trigonal ligand field fall in the range of the experimental values. The dipolar shifts for d1 and d2 complexes in a strong trigonal ligand field are also calculated using the calculated magnetic susceptibility components. The calculated values of the dipolar shifts also fall in the reasonable range.

[学科分类] 化学（综合）