Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization
[摘要] The complex of iron(�?) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen)3](PF6)2·CH3CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of [Fe(3-Br-phen)3]2+ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-[Fe(3-Br-phen)3]2+ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.
[发布日期] [发布机构]
[效力级别] [学科分类] 化学（综合）
[关键词] Electropolymerization;Poly-[Fe(3-Br-phen)3]2+;Glassy carbon disk electrode;X-Ray crystal structure;Absorption spectroscopy. [时效性]
