Crystallization of 𝑀-type hexagonal ferrites from mechanically activated mixtures of barium carbonate and goethite

[摘要] 𝑀-type hexagonal ferrite precursor was prepared by a soft mechanochemical treatment of BaCO₃ and ð›�?-FeOOH mixtures. The effect of milling on its structure and thermal behaviour was examined by XRD, SEM and FTIR. Well crystallized 𝑀-type hexagonal ferrite was formed from just 1 h milled precursors at 800°C. The beneficial effect of milling was explained in terms of increased homogeneity with simultaneous hetero bridging bond formation between powder constituents.

[学科分类] 材料工程

[关键词] ð‘€-type hexagonal ferrite;mechanical activation;powder;crystallization.