Intriguing Salt Effects in the Formation of Hydroxamic Acids from Aldehydes and Nitroso Compounds

[摘要] Addition of inorganic chlorides and perchlorates into the reaction mixture in water leads to a significant increase of the rate constants observed for the formation of N -phenyl hydroxamic acids from nitrosobenzene and formaldehyde or...

[学科分类] 化学（综合）

[关键词] salt-effects;ion-pairs;hydroxamic acids;hydroxamates;kinetics