The Vibrational Stark Effect on the Doubly Degenerate ν19 Modes of the Benzene Guest Molecules in Hofmann Type Clathrates

[摘要] An alternative mechanism is proposed for the observed splitting of the ν 19 γ(CH) mode of the benzene guest molecules in Hofmann type clathrates to the one presented previously. 1 According to the proposed model, the splitting...

[学科分类] 化学（综合）

[关键词] vibrational Stark effect;Hofmann clathrates;host-guest interactions;electrostatic field induced degenerate mode splitting;...