Rhyolitic volcanism in the Onverwacht Group, Barberton Greenstone Belt

[摘要] ENGLISH ABSTRACT: The source of the K2O in the K2O-rich ~3.45 Ga felsic intrusive rocks of the H6 unit in the Hooggenoeg Formation of the Onverwacht Group in the Barberton Granite Greenstone Terrain (BGGT) is examined in this study. This is of particular research interest because the Paleoarchaean rock record is considered to lack K2O-rich magmatic rocks. Previous studies on the felsic igneous rocks of the H6 unit have proposed that these rhyolites are K-metasomatised eruptive equivalents of the sodium-rich ~3.45 Ga TTGs of the BGGT and that the K-feldspar crystals in the rocks formed as a consequence of subsolidus replacement of plagioclase by K-feldspar. Furthermore, the timing of K-metasomatism has previously been related to the formation of the Buck Ridge Chert (BRC), which overlies the H6 unit. However, it has recently been demonstrated from granitic clasts in the conglomerate layer at the base of the Moodies sucession that K2O-rich magmatic rocks formed concurrently with TTG magmas during each of three episodes of TTG magmatism observed in the BGGT. Consequently, the hypothesis of a metasomatic origin for the K2O-rich character of the felsic rocks of the H6 unit requires further examination.Previous studies of the chemistsry of felsic volcanic rocks within the H6 unit were based on relatively low numbers of samples. This study has examined a substantial set of the freshest material available. Two varieties of felsic volcanic rocks were identified; K2O-rich, CaO-poor, Na2O-poor rhyolites and Na2O-rich, CaO-poor, K2O-poor Na-rhyolites. The K2O- rich rhyolite variety is dominant.Consequently, it is possible that the K2O-rich character of these rocks represents a primary magmatic signature. However, this judgment is complicated by the presence of a greenschist-facies metamorphic overprint at 3.2 Ga, which has resulted in complete replacement of micrystalline groundmass and partial replacement of the phenocryst assemblages by greenschist- and sub-greenschist-facies mineral assemblages, which undoubtedly allowed possible shifts in chemical compositions In this thesis, I test the source of K2O in these rocks by using the porphyritic textures of the rocks as an indication of the primary composition of the magmas they were formed from. These textures are typically defined by K-feldspar or albite and quartz phenocrysts within a microcrystalline groundmass. The rocks containing albite are Na-rich (Na-rhyolites) whereas the rocks defined by K-feldspar phenocrysts are rhyolites. XRD study of the structural state of the K-feldspar phenocrysts in the rhyolites indicates that these crystals are orthoclase and intermediate microcline, i.e. medium temperature K-feldspar polymorphs. The modal proportions of K-feldspar, quartz and microcrystalline groundmass in the rhyolites were calculated by using image analysis software. The compositions of the feldspar minerals were determined by electron beam analysis. Minimum bulk rock K2O content of the rhyolites were calculated from the proportions of K-feldspar crystals and their compositions. Even where the proportion of K-feldspar phenocrysts is relatively low (~ 30%), the calculated minimum bulk-rock K2O content is still above 5 wt%. The HREE slope (GdN/LuN) of the felsic porphyritic rocks of the H6 rhyolites is similar to that of ~3.45 Ga TTG plutons and steeper than that of granitic clasts of identical age contained in the basal conglomerate of the Moodies Group. Hence this study has illustrated that the rhyolites of the H6 unit were primary K-feldspar-rich, K2O-rich magmas that formed contemporarily with the ~3.45 Ga TTGs. This implicitly means that rhyolitic volcanism was more wide spread than previously thought in the Paleoarchaean and that it occurred together with the intrusion of the ~3.45 Ga TTGs in the BGGT.

[发布机构] Stellenbosch University