Solubility of sparingly-soluble electrolytes–a new approach

[摘要] The technique of solid titration was developed to explore the true solution equilibria for complex solids and solutions, and in particular for biominerals. It has been shown that the conventional method of equilibration over a large excess of solid is inappropriate for the investigation of solubility when there is incongruent dissolution. The new method shows great sensitivity, reliability and reproducibility, and can be applied to many systems in medical and dental contexts, as well as general chemistry, geology, and the pharmaceutical industry...

[学科分类] 分析化学