Rh(III)‐catalyzed ortho‐Alkylation of N‐Benzyltriflamides with Diazo Compounds

[摘要] The rhodium(III)‐catalyzed ortho‐CH functionalization of N‐benzyltriflamides with α‐diazo compounds is described. This transformation provides the facile construction of C2‐alkylated N‐benzyltriflamides in the absence of external oxidants under mild reaction conditions.

[学科分类] 化学（综合）

[关键词] Alkylation; N‐benzyltriflamides;CH activation;Diazo compounds;Rhodium