Crystal structure of dimethyl-1κ2C-bis(μ-4-methylphenolato-1:2κ2O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ2N,N′)indium(III)lithium(I)

[摘要] The mixed bimetallic title compound, [InLi(CH3)2(C7H7O)2(C6H16N2)] or [(tmeda)Li-μ-(4-MeC6H4O)2InMe2] (tmeda is N,N,N′,N′-tetra­methyl­ethylenedi­amine), exhibits a four-membered LiO2In ring core via bridging 4-methyl­phenolate groups. The Li and In atoms are in distorted tetra­hedral N2O2 and C2O2 bonding environments, respectively. The Li atom is further chelated by a tmeda group, yielding a spiro­cyclic structure.

[学科分类] 数学（综合）

[关键词] CRYSTAL STRUCTURE;BIMETALLIC;INDIUM;LITHIUM;PHENOLATE;SPIROCYCLIC