Synthesis of reactive and stimuli-responsive polymer thin films by initiated chemical vapor deposition and their sensor applications
[摘要] (cont.) The final two projects involved the synthesis of polymer thin films as chemically selective layers in microscale chemical sensors. In a sensing system based on the detection of amine compounds through their reaction with reactive polymer coatings on microcantilevers, it was shown that increased crosslinking of the polymer layer leads to greater cantilever deflection. This increased deflection enabled the design of simple, resistance-based signal readout schemes with low power requirements. New polymer compositions and sensing strategies were also developed for the detection of nitroaromatic explosives vapors. Poly(4-vinylpyridine) was shown to swell when exposed to nitroaromatics, while showing little response to common interferents. In contrast to conventional nitroaromatic-selective layers, it was shown that poly(4-vinylpyridine) does not interact with nitroaromatics through hydrogen bonding, which is important for multicomponent sensor arrays. A new microscale sensing concept utilizing this swelling was designed, fabricated, and characterized.
[发布日期] [发布机构] Massachusetts Institute of Technology
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