Structure Crystal of (N-Methyl benzyl Dithiocarbamate) dibutyl Tin (IV).
[摘要] (N-methylbenzylTin(IV) dithiocarbamate has been synthesized and characterized, the compound isprepared from the reaction between the 4-methylbenzyl amine dissolved in absolute ethanol with carbondisulfide in absolute ethanol with the same ratio of 0.2 mmol, the mixture of this compound was added to themetal dibutyl tin (IV) dichloride in an ethanol solvent, then distirer for 2 hours. resulting in the formation ofprecipitate, then filtered and recrystallized with a mixture of ethanol with chloroform with a ratio of 1: 1. Thecrystals formed were chelate octahedrons with 6 coordinates with a dithiocarbamate league binding of anisobidentat, the results of the crystallographic test show that the compound formed is octahedron distorted,resulting in a new compound N-methylbenzyl ditiocarbamate dibutyl Tin (IV).
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[效力级别] [学科分类] 工程和技术(综合)
[关键词] benzyl dtc;methyl;crystal structure. [时效性]