Large magnetic circular dichroism in resonant inelastic x-ray scattering at the Mn L-edge of Mn-Zn ferrite

[摘要] We report resonant inelastic x-ray scattering (RIXS) excited by circularly polarized x rays on Mn-Zn ferrite at the Mn L-2,L-3 resonances. We demonstrate that crystal-field excitations, as expected for localized systems, dominate the RIXS spectra and thus their dichroic asymmetry cannot be interpreted in terms of spin-resolved partial density of states, which has been the standard approach for RIXS dichroism. We observe large dichroic RIXS at the L-2 resonance which we attribute to the absence of metallic core hole screening in the insulating Mn ferrite. On the other hand, reduced L-3-RIXS dichroism is interpreted as an effect of longer scattering time that enables spin-lattice core hole relaxation via magnons and phonons occurring on a femtosecond time scale.

[发布日期] 2006-11-01

[关键词] EMISSION;FLUORESCENCE;PHOTOEMISSION;SPECTROSCOPY;FE;RADIATION;ENERGY;IRON;MCD;2P